Why benzene undergoes electrophilic substitution reactions why not addition

 

Benzene organic chemistry b pharmacy



Why benzene undergoes electrophilic substitution reactions why not addition?

Both benzene and alkenes are susceptible to electrophilic attack because of their exposed Ï€
 
electrons. both react with electrophiles to form stable carbonium ions. 

Electrophilic addition of benzene

The carbonium ion produced from the alkene usually combines with a nucleophile to give the overall addition product.

Organic chemistry benzene b pharmacy

The resonance energy of benzene would be lost. instead, the nucleophile removes a proton from the carbonium ion intermediate. the loss of proton allows the electrons from the C - H bond to go back into the ring and regenerate the automatic Ï€ system, net charges is the replacement of a hydrogen atom by an electrophile.

Organic chemistry b pharmacy







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